Gas Phase Silver Thermochemistry from First Principles
نویسندگان
چکیده
منابع مشابه
The gas-phase thermochemistry of TiH
The homolytic bond dissociation energy of the titanium neutral hydride D ‘(Ti-H) is determined experimentally for the first time by using guided ion beam tandem mass spectrometry to measure the kinetic energy dependence of the endothermic hydride abstraction reactions of Ti+ with methylamine, dimethylamine, and trimethylamine. From the thresholds of these reactions, the value of D ‘(Ti-H) = 2.1...
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The homolytic bond dissociation energies of the transition-metal neutral hydrides, D’(M-H) (M = V, Cr) , are experimentally determined by using guided ion beam tandem mass spectrometry to measure the kinetic energy dependence of the endothermic hydride abstraction reactions of M+ with mono-, di-, and trimethylamine. From the thresholds of these reactions, we derive the 0 K values of DO(V-H)=2.1...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2019
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.9b00556